Integrated Gas Diffusion Layer With Sealing Function And Method Of Making The Same

ABSTRACT

Techniques and implementations pertaining to an integrated gas diffusion layer with a sealing function are described. A method for making the integrated gas diffusion layer with the sealing function may involve placing a gas diffusion member inside a mold followed by injecting a sealing material into the mold. The method may also involve having the sealing material substantially covers a peripheral portion of the gas diffusion member and at least partially penetrates into a peripheral portion of the gas diffusion member. The method may further involve curing the sealing material to form a sealing member having a lip ring. A height of a portion of the mold corresponding to a non-lip ring portion of the sealing member is less than or equal to a thickness of the gas diffusion member.

CROSS REFERENCE TO RELATED PATENT APPLICATION

The present disclosure is a divisional that claims the priority benefitof U.S. patent application Ser. No. 13/904,801, filed 29 May 2013, whichis incorporated by reference in its entirety.

TECHNICAL FIELD

The present disclosure relates to fuel cells and, more particularly,relates to integrated gas diffusion layers with a sealing function andmethods of making the same.

BACKGROUND

Fuel cells are devices that can convert chemical energy directly intoelectrical energy through electrode reaction of hydrogen and oxygen. Afuel cell typically includes multiple fuel cell units. Each fuel cellunit includes two electrodes (anode and cathode) separated from oneanother by an electrolyte material. The fuel cell units are stacked inseries to form a fuel cell stack. An electrochemical reaction occurs asappropriate reactants are supplied to each electrode, i.e., the fuel issupplied to one electrode and the oxidant is supplied to the otherelectrode, thereby creating an electrical potential difference betweenthe two electrodes. As a result, electrical energy is generated.

The core of the fuel cell is the fuel cell stack. Two ways to supplyreactant gases to the fuel cell stack are presently known in the art.The reactant gases are supplied through common manifolds located eitherinside the fuel cell stack or outside the fuel cell stack. When gasesare supplied through the common manifolds inside the fuel cell stack,the battery needs to be sealed to prevent leakage of the reactant gasesand coolant as well as the mixing of the fuel, the oxidant, and thecoolant through the common manifolds.

Ballard Inc.'s U.S. Pat. No. 5,284,718 describes placing sealingstructures on the membrane electrode assembly (MEA) having a dimensionthe same as that of the bipolar plates. The MEA has three inletthrough-openings and three outlet through-openings. Grooves are formedaround peripheries of the through-openings and edges of the MEA in whichthe sealing structures are disposed. However, this approach is notsuitable for thinner membranes. Based on the disclosure therein, ChinesePatent No. ZL200580042454 describes a sealing structure circumscribingthe MEA. This may solve the limitation on the membrane thickness;however, due to the low utilization efficiency of the proton exchangemembrane, waste may be incurred.

Another approach is to place sealing structures on bipolar plates byforming grooves around the peripheries of common manifolds and edges ofthe bipolar plates. The sealing structures are then disposed in thegrooves. One drawback of this approach is the increased requirements forthe sealant. The sealant, if penetrating into the reaction zone in thegas diffusion layer, may result in an increase in the concentrationpolarization.

The conventional way to make MEA is to adhere an insulatingstrengthening material to both sides of the proton exchange membrane toincrease the strength of the proton exchange membrane. However, thismanufacturing process is very complicated and time-consuming, and thusis not suitable for mass production.

SUMMARY

In order to solve the aforementioned problems, the present disclosureprovides a non-traditional seal approach. Herein, the sealing materialis provided on neither the bipolar plates nor the MEA, rather thesealing material is integrated with the gas diffusion layer.

In one aspect, an integrated gas diffusion layer with a sealing functionis provided. The integrated gas diffusion layer may comprise a gasdiffusion member and a sealing member substantially covering aperipheral portion of the gas diffusion member. The sealing memberhaving fuel inlet and outlet openings, oxidant inlet and outletopenings, and coolant inlet and outlet openings.

In one embodiment, the sealing member may at least partially penetrateinto the gas diffusion member at contact areas of the sealing member andgas diffusion member, thereby connecting the sealing member to the gasdiffusion member.

In one embodiment, the sealing member may be affixed to the gasdiffusion member by adhesive bonding.

In one embodiment, the sealing member may comprise a lip ring having alip portion that is raised from the sealing member. The lip ring may beconfigured to be fitted into a sealing groove on a bipolar plate.

In one embodiment, the sealing member may be made of a rubber, athermoplastic elastomer, or a thermosetting injection molding liquidsilicone rubber.

In one embodiment, the gas diffusion member may be made of a carbonpaper or a porous electrically conductive material.

In another aspect, a method of making an integrated gas diffusion layerwith a sealing function is provided.

In one embodiment, a method of making an integrated gas diffusion layerwith a sealing function may comprise the following steps: placing a gasdiffusion member inside a mold; after clamping the mold, injecting asealing material into the mold such that the sealing materialsubstantially covers a peripheral portion of the gas diffusion memberand at least partially penetrates into a peripheral portion of the gasdiffusion member; and curing the sealing material to form a sealingmember having a lip ring. The height of a portion of the moldcorresponding to a non-lip ring portion of the sealing member is lessthan or equal to the thickness of the gas diffusion member.

In another embodiment, a method of making an integrated gas diffusionlayer with a sealing function may comprise the following steps:providing a hollow region in a central part of a sealing member;covering the hollow region substantially by a gas diffusion member; andaffixing the sealing member to the gas diffusion member by adhesivebonding at overlapping regions of the sealing member and the gasdiffusion member. The hollow region has an area slightly smaller thanthe gas diffusion member.

The sealing member may be made of a rubber, a thermoplastic elastomer,or a thermosetting injection molding liquid silicone. The gas diffusionmember may be made of a carbon paper or a porous electrically conductivematerial.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a top view of an integrated gas diffusion layer in accordancewith the present disclosure.

FIG. 2 is a cross-sectional view of the integrated gas diffusion layerin accordance with the present disclosure.

FIG. 3 is an enlarged cross-sectional view of the integrated gasdiffusion layer in accordance with one embodiment of the presentdisclosure showing a penetration portion formed at the contact area ofthe sealing member and the gas diffusion member.

FIG. 4 is a schematic view of a fuel cell unit in accordance with thepresent disclosure.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

The present disclosure is described below in more detail with referenceto the accompanying drawings.

Embodiment 1

In the present disclosure, thermosetting injection molding liquidsilicones, such as Liquid Silicone Rubber (LSR) are used to make thesealing member, and carbon papers are used to make the gas diffusionmember.

A carbon paper is placed in a hot mold. Injection molding liquidsilicone rubber LSR is fed into a hot mold through a cold runner. Thetemperature of the hot mold is kept between 140° C. and 200° C. Afterfilling the mold with the silicone rubber, the silicone rubber is curedfor 50-60 seconds. The resulting integrated gas diffusion layer isremoved from the mold.

Referring to FIGS. 1 and 2, the integrated gas diffusion layer after thecuring process includes a gas diffusion member 1 and a sealing member 2.The sealing member 2 is provided with fuel inlet and outlet openings4-1, 4-2, oxidant inlet and outlet openings 6-1, 6-2, and coolant inletand outlet openings 5-1, 5-2. The peripheral portion of the gasdiffusion member 1 is at least substantially or completely covered bythe sealing member 2. As shown in FIG. 3, since the gas diffusion member1 is made of a porous material, the sealing material may penetrate intothe gas diffusion member 1 at the contact area 120 of the sealing member2 and the gas diffusion member 1, thus forming an integrated structure.The penetration results in a transverse sealing (indicated by the blackarrow) in the contact area 120. In this way, no water or gas canpermeate through the contact area 120. The sealing member 2 alsoincludes a lip ring 3 having a lip portion that is raised from thesealing member 2.

In one embodiment, the material for the sealing member 2 is silicone orthermoplastic elastomer, or thermosetting injection molding liquidsilicone rubber.

In one embodiment, the material for the gas diffusion member 1 is carbonpaper or a porous electrically conductive material. After injectionmolding, the sealing member 2 except the lip ring portion thereof has athickness less than or equal to a thickness of the gas diffusion member1.

Referring to FIG. 4, a fuel cell unit 11 may comprise two integrated gasdiffusion layers 7 sandwiched between a cathode plate 8 and an anodeplate 9, and a MEA 10 disposed between the two integrated gas diffusionlayers 7. Each of the fuel inlet and outlet openings, the oxidant inletand outlet openings, and the coolant inlet and outlet openings formed oneach of the integrated gas diffusion layers 7 corresponds to arespective one of the three inlet openings and three outlet openingsformed on the corresponding bipolar plate (cathode plate 8, anode plate9) . The lip ring 3 on each of the integrated gas diffusion layers 7corresponds to the sealing groove formed on the corresponding bipolarplate. When the fuel cell unit 11 is pressed, the lip ring 3 on each ofthe integrated gas diffusion layers 7 is fitted into the sealing grooveon the corresponding bipolar plate. The sealing member 2 of each of theintegrated gas diffusion layers 7 comes to rest against thecorresponding bipolar plate and the MEA, thereby sealing the bipolarplates and the MEA.

The surface area of each of the gas diffusion member 1 in the integratedgas diffusion layers 7 is greater than both the catalyst coating on theMEA and the reaction area of the flow channel on the bipolar plate.Thus, although the sealing material penetrates into the peripheralportion of the gas diffusion member during the injection molding andcuring processes, after excluding the sealant penetration area, theremaining active area of the gas diffusion member is still greater thanor equal to both the catalyst coating on the MEA and the reaction areaof the flow channel on the bipolar plate. As a result, the reaction areaof the electrode assembly is not reduced.

The sealing member 2 of the present embodiment may be made of silicone,thermoplastic elastomer, or thermosetting injection molding liquidsilicone rubber. For different sealing materials, the injectiontemperature and time or the curing temperature and dwell time may bedifferent.

Embodiment 2

The present embodiment is similar to Embodiment 1. One difference is themanufacturing process of the integrated gas diffusion layer.

Referring to FIG. 1, the sealing member 2 in the integrated gasdiffusion layer with a sealing function of the present embodiment has ahollow region situated in the central part of the sealing member 2. Thearea of the hollow region is slightly smaller than that of the gasdiffusion member 1, thus the hollow region is at least substantially orcompletely covered by the gas diffusion member 1. The integrated gasdiffusion layer is formed by adhering the gas diffusion member 1 and thesealing member 2 together at overlapping regions by adhesive bonding.The sealing member 2 also includes a lip ring 3 having a lip portionthat is raised from the sealing member 2.

All the materials used in the present embodiment are the same as thoseused in embodiment 1.

One of advantages of the present disclosure is that the current designin which the gas diffusion layer and the sealant are integrated avoidsthe possible shedding of the seals, while at the same time it willincrease the seal strength. In addition, the two sealing members aredisposed respectively between the anode plate and the MEA as well as thecathode plate and the MEA, thus the seal performance can besignificantly improved. Furthermore, since there is no need to placeinsulting strengthening films on both sides of the proton exchangemembrane, such design can greatly improve production efficiency andreliability.

Moreover, as to the conventional method in which the gasket isintegrally formed with either the bipolar plate or the MEA, since themanufacturing costs of the bipolar plate and the MEA, especially theMEA, are rather high, if the bipolar plate or the MEA is damaged duringthe integration process, the manufacturing cost of the whole fuel cellwill be greatly increased. This problem can be effectively solved by theintegration of the seal and the gas diffusion layer.

What is claimed is:
 1. A method of making an integrated gas diffusionlayer with a sealing function, comprising: placing a gas diffusionmember inside a mold; injecting a sealing material into the mold suchthat the sealing material substantially covers a peripheral portion ofthe gas diffusion member and at least partially penetrates into aperipheral portion of the gas diffusion member; and curing the sealingmaterial to form a sealing member having a lip ring, wherein a height ofa portion of the mold corresponding to a non-lip ring portion of thesealing member is less than or equal to a thickness of the gas diffusionmember.
 2. The method of claim 1, wherein a contact area between thesealing material and the gas diffusion member is created by the sealingmaterial penetrating into the peripheral portion of the gas diffusionmember, and wherein the contact area creates a transverse sealing thatprevents water and gas from permeating through the contact area.
 3. Themethod of claim 1, wherein the sealing member comprises a rubber, athermoplastic elastomer, or a thermosetting injection molding liquidsilicone rubber.
 4. The method of claim 1, wherein the gas diffusionmember comprises a carbon paper or a porous electrically conductivematerial.
 5. The method of claim 1, wherein the lip ring has a lipportion raised from the sealing member and comprises a continuousintegral piece.
 6. The method of claim 1, wherein the curing of thesealing material to form the sealing member comprises keeping the moldbetween 140° C. and 200° C.
 7. The method of claim 1, wherein the curingof the sealing material to form the sealing member comprises curing thesealing material for 50-60 seconds.
 8. The method of claim 1, whereinthe injecting of the sealing material into the mold comprises injectingthe sealing material into the mold through a runner having a firsttemperature lower than a second temperature of the mold.
 9. A method ofmaking an integrated gas diffusion layer with a sealing function,comprising: providing a hollow region in a central part of a sealingmember; covering the hollow region substantially by a gas diffusionmember; and affixing the sealing member to the gas diffusion member byadhesive bonding at overlapping regions of the sealing member and thegas diffusion member, wherein the hollow region has an area slightlysmaller than the gas diffusion member.
 10. The method of claim 9,wherein the sealing member comprises a rubber, a thermoplasticelastomer, or a thermosetting injection molding liquid silicone rubber.11. The method of claim 9, wherein the gas diffusion member comprises acarbon paper or a porous electrically conductive material.